{"schema":"pubphys.bundle/1","record":{"author":{"account_ref":null,"orcid":null},"builds_on":[],"content_schema":"pubphys.content.revision/1","content_sha256":"cf73d9c9b91edd96dac93b20b67e49128930faca72c0cf0c2bb9b9215ca69bc5","created":"2026-10-03T07:17:55Z","files":[],"origin":{"assisted_by":[],"kind":"seed"},"parents":["5475cf5dc5b1a72283d26dc95dc6e00d7ea4e00096a7c6492e409a1816eeb011"],"salt":"c5f173da441140407a0eae63592af0cedffeb722d6f5fce26b5104c5eadeae0d","schema":"pubphys.record/2","site":"pubphys.com","target":null,"type":"revision"},"content":{"answer_type":"identification","assisted_by":[],"external_id":"astro.ism-astrochemistry.dib-carriers","kind":"well-posed","literature_status":"open","n":"1","parents":[],"plain":"Starlight crossing interstellar gas shows hundreds of absorption bands, called diffuse interstellar bands, whose source is unknown. After a century, only one molecule, the positively charged buckyball C60+, has been confirmed.","posed_since":"","precise":"Of more than 500 known diffuse interstellar bands in the $4000\\ \\text{to}\\ 13000\\ \\mathrm{Angstrom}$ range, only the C60+ bands (strongest near $9577\\ \\text{and}\\ 9632\\ \\mathrm{Angstrom}$, weaker ones near $9365\\ \\text{and}\\ 9428\\ \\mathrm{Angstrom}$) are securely assigned, by cold gas-phase laboratory spectroscopy. Identify the carriers of the remaining bands, requiring a laboratory gas-phase spectrum matching wavelengths, widths and relative strengths at interstellar temperatures.","problem_ref":null,"references":"","settled_by":"Cold gas-phase laboratory spectra of candidate molecules matching the strongest unassigned bands (5780, 5797, 6284 Angstrom) in position and profile.","status_note":"Cyclic C4+ was proposed in 2025 for the 5039 Angstrom band (Krasnokutski et al., ApJ, 2025) and remains unconfirmed.","title":"Which molecules cause the diffuse interstellar bands?","topic_ref":"053938143b301dc6b1d81522aef24ce54269bd5a5c046d77683dda38966086a5"},"content_withheld":"false","files":[],"attested":{"attestation":{"batch":null,"client_id":null,"id_token_sha256":null,"kind":"platform"},"record_hash":"1979afbb27937c44735a1d77a8fd1ecd493bb545f58bbd8c457f40d2053826a9","schema":"pubphys.attested/1"},"id_token":null,"id_token_withheld":"false","envelope":{"attested_hash":"433ddac75b6496123a57b7029aba6d7b6a13d4c89e81fd415e40172837945386","platform_signature":{"key_id":"c6afc19b31429869751f06879c75cd64ea92654423d15b44be775bf1310a60da","sig":"k4EkWa4qs8_HC7NTs9f91XthHVr22IBNPnFJQDJh-HisXrwAtTsNUM3d9mV1H6EPwH4nUEpJwsUyQ8zuOWiqAA"},"schema":"pubphys.envelope/1"},"ots":{"attested":["AE9wZW5UaW1lc3RhbXBzAABQcm9vZgC_ieLohOiSlAEIQz3ax1tklhI6V7cCmrpte2oT1Miegf1BXkAXKDeUU4bwIENaJhx3CyDXQj44PXoWuiUzb52K4OjfynrP0wjFXNu3CPEgG0DFI-I34MoBZaYlQhoaqr2awEkbvt3zXXydFiu-180I8SCdxORkmfUt5qaTip2li3ZQgOUAGJR1uNpHXp4-XGvgpAjxIJphdr4jMWn6slCujz72wk3U5jujg9cpc3CCvtiPAO9lCPEgK_d_8zdEcfISquWAJNYVPrLwKgaDhBd3IwCg-Mf_ARAI8CDKsWHDHNsx3QdsCed_B37GDBKSRVPEFrxfbyRJte1H0gjxIO0D7CRgiEuDrwg_IQ4Djq6tg8Px2LVb4_GnOkvNiXBICPAgDwiS_6mbTnnYK_oMGqQLov2YRVYIj9Er1NWLuDHHhV8I8CDcBxRb7fDApTWNNvjZ_r2lDpQT60DYte3pStKjciGgOAjwIK9SXvHBwgJE5CknXtp2lOqKcbHlJ-ncP9sNjnTHUJsmCPEgytIBB3x7TFDT-XqOV-9vpqw1NKoAu0dhtsCbAMql2L0I8CCtNZgmApuKULvPC9nsMCaM05arV-F3o5FTlnJCnRvdMgjwIBGYo5Vxy-d7U5zKv5vp3Ii7hJPH_BDLCzA13c47p9q7CP_wCHbghVgOFMuNCPAQPZK2lHbTMqcCYUotzOQcmQjwIJ7ruRIs6HnufKxCpmLUgeUl0aUu0ov4_3PqcppS-bddCPEgI530vHzdwz_3o9jYQ3WablSaV64Wfn7Pmby5WLyI-A0I8QRqwKw78AhITF7Tr3a1xP8Ag9_jDS75DI4sK2h0dHBzOi8vYm9iLmJ0Yy5jYWxlbmRhci5vcGVudGltZXN0YW1wcy5vcmcI8CBXWeNiWFWltfHE0nkDXsVKIykUUwuObhsnN-2fvBt98gjwIM5Vf7j68sOFgVysYMc5S09Hho-fqxYW3oQ4oKUX7JpPCPAgaKHHQB3sdd9w1hu4NMh7vmb-p0X2r4uyVKKCj1G7S28I8SAW2Mg6Bzi9ygjrrjIYB7w90fwMcxH24SsqLmzPyAMGfwjwIMQ863zlveYIpNKWVrZaDOa4vowwoOg2CcTW8gXtxK3dCPEgrZxGGAf-t8jhz_eLMUyBN1IhNrdYDRcNHWvQcwNG9woI8CCVOUHG1YXudbaFIgUYvrCIevRWvb2ubhQAo-z0duD0rQjxIDBeKerVGkO3J2eXDwdraSioXbIWsdIPEN1s8pIwJIS2CPAgV2kB3n3JZ5HwBQjpRL1CWKnqvdCjZk3RcALk6N2wHigI8CB-wbljNlfqElD25uZkNg6taS81YDRU2vfMqGVQ420O9AjxWQEAAAABJM43UU6MLMRrPlCUqossvu1q_knons5yylyWTgxZzWUAAAAAAP7___8CLgABAAAAAAAWABQrYt3E7OllKRCEmL3FL589l78_5wAAAAAAAAAAImog8ATiyw4ACAjxILmbcIO7ixv3pCtwUMZ1VQGKus54F9lZ8-w5ECD5ZuiICAjwIG6ynCyFTLPE7Rgk-0ZGCtBDyqNQx8YvaSZNHy8D8p8jCAjwIMX8zoD2Be1YWvcx_bexVPRmBX0hK-do8b8t9SarimQVCAjxIG6XtpqIEclLlhzcK1LVjqoPGrjjmLnyno8tcETMzECECAjwIF6mlfXOFY51JhrK4eze8zQlKV75OYZYqbtyi8BWxmAsCAjwIKKUcJmVoz-u-geiRV_-ZHdF0VEPXaEPFWf_JX_0e7G2CAjxIGMeD0Z5QWNKBcAEpHht007FFIILW6aSJ8f3CMkKNsneCAjwIBFr6Je8rkB7kwhPGbq0yRgFwZsvW9JhY5sXDRtrq0QwCAjwIAHAwXaus-yUgKICJB5mVvx8VZuJgjwnpb0qWPg1pi6DCAjxIAJhb8cefkVHTAMymdsxa-_i-tUua62LcpALQnPG7R9_CAjwIDvsFqBhPfAL6TCtXZd7gBWmMpx6iiZ-Ug0Jf_LlcstgCAjwIDJRBX6Q0Vge-ra-k1_g76yJWTEp6WWF13I3JpTnsZPJCAjwILykZCbkC9VQgl5gytPKKir6T9nTvKR6y05iWSHBTQgzCAgABYiWDXPXGQED45c78Ah-sGbmQAwfZwjwEAYqxtHnZiPZnJEGPx_JvKsI8SDXkqDg17YsZIrEz5acRx7mBXCKW5mKNgRYnw_-U2cpDgjxBGrArDrwCEfK6Mono428_wCD3-MNLvkMji4taHR0cHM6Ly9hbGljZS5idGMuY2FsZW5kYXIub3BlbnRpbWVzdGFtcHMub3JnCPAg10nyJ6Jn4kshQQQCKE0Lvj3hBC6nLRBVIzaPV4eh8VwI8CCQaAqWlxEbac_XOq1MOlf9iOKHEsxXspzbjK0vLpy8BwjwII3iRbRXUcDxrhAdkZmFlI15nySCSEZ7g922tF1Xln5DCPEgYYvZ1L4v4rPu_UqLfcHPtwSb2OH2GhPgVcVhhH6DpkQI8CDZCIoR20sC-uchP40oAmcLm9EJFV7xzwplj54AeVadXQjxILvLBjPFpCoz29m9Yf2qRnV7PI9GqxE8ozVQfk9QwCqrCPEgZXcMudvEoB_MJ8tqOW2PLTKAIeQBnE-1bfzptRc2gR8I8VkBAAAAAfXq-bmxWqOz7B5wKkwjzHGv2R4s7Y0Z76LqXWYNhmz0AAAAAAD-____Av0cAAAAAAAAFgAUl-skmdZDtn7Hnub6mF4HP2uVn7oAAAAAAAAAACJqIPAE4MsOAAgI8CBDmQsbEXc46Hu8DivhCBM1LGExa4TTM-wo7HpoCVjBTQgI8CCty5vkQtPHzzs8xqArOYhVSjgaDoG1ou3cojv5_P7wQQgI8SDQWB0kdXCTwbk-TqTt0QfRMyzDNLOtU1XXFgvGSRlW8wgI8CC2PKa_QCIBZtrXodq1GdEzppISMsMRDOnzr2gFjLKOAAgI8CCwQ_QF67bcFk_uJ2s0VCZmf5PGIjTmTCpt_qnVY5p_8AgI8SAbzyx7z-oxPMju6PvtQhzrJIQyH2ZAc9oyLuYemzbmZQgI8CC5bh7J74uUk91r8LwybHQFCNBC3PWeuwtMCCNFKWj19AgI8SAf4R2TUNPjaX_PWDUImpoITK0JoW89zaMKnD1wlEEi8AgI8SC2vNmdm7eyP5Ytl1yTzT0njliMdALl1ViKG-s3bG2zswgI8CCpbIVNz1GFVXdJk2zd82hBUoNFFemUPBt7IJdWEOciPwgI8CBtYdRQcrtX1FtCm1SxF7sx-5cO04U8KzbJh8fqBkyReAgI8CBHs2LGmX6gI-lV7yp1RrV7_tGfdiBAwnEFF6B6yXHzAQgI8CATotVmbXBMAixhZ-QKy5Q4lR0FusdA_wcIC1TbB7GmxAgIAAWIlg1z1xkBA-KXOw"],"envelope":["AE9wZW5UaW1lc3RhbXBzAABQcm9vZgC_ieLohOiSlAEIBrz5y4qnhOx3zP9f_Zd0ZKumvuAQUBN3kDGDQMacyETwIAbLs3ZkkG0UhaZXUqlAc3woLFW1T2Aedoi7IGXT9oLOCPEgoQ5qGP6MuR704fRkkp2MMujDVZd3A8XPHDacOrM2DrAI8SDYv3rUanq8WYQOivRJQb2sQhpIQw6Ee61Yiga7mIwlOQjxIOPaqDFmxvxqxwkufY2h6bIz9OZO3GHhX2EcRirzr7VECPAg1m5895SFgvir13wGXz4Y4v1sZAEz6iHELE15PKY4BFwI8SAsOHgtAgzo5j_83otKbuYlvM80JCmkAciAYK2kWQv7IQjxICX4sWXZiUHn7v-zJ5hXalBcsa_hpGm08g9aBpaZojnECPAgNl1YNYfZwu98LlVobqGe3qyzw872nZef7-vqHE3nXn0I8CDTURm5psgkpndkZlRIia_PxrzHEbIi4fWR0w8YEe9YLAjwIMIc4xq7iJ2YP27EtWYUvEm4-TQD7cayDq2XvZh74n3BCPAg3v2QXfNkDO6Xzu9061umH0rhjRfHBKza3uG2nPQbpd8I8CCtNZgmApuKULvPC9nsMCaM05arV-F3o5FTlnJCnRvdMgjwIBGYo5Vxy-d7U5zKv5vp3Ii7hJPH_BDLCzA13c47p9q7CP_wCHbghVgOFMuNCPAQPZK2lHbTMqcCYUotzOQcmQjwIJ7ruRIs6HnufKxCpmLUgeUl0aUu0ov4_3PqcppS-bddCPEgI530vHzdwz_3o9jYQ3WablSaV64Wfn7Pmby5WLyI-A0I8QRqwKw78AhITF7Tr3a1xP8Ag9_jDS75DI4sK2h0dHBzOi8vYm9iLmJ0Yy5jYWxlbmRhci5vcGVudGltZXN0YW1wcy5vcmcI8CBXWeNiWFWltfHE0nkDXsVKIykUUwuObhsnN-2fvBt98gjwIM5Vf7j68sOFgVysYMc5S09Hho-fqxYW3oQ4oKUX7JpPCPAgaKHHQB3sdd9w1hu4NMh7vmb-p0X2r4uyVKKCj1G7S28I8SAW2Mg6Bzi9ygjrrjIYB7w90fwMcxH24SsqLmzPyAMGfwjwIMQ863zlveYIpNKWVrZaDOa4vowwoOg2CcTW8gXtxK3dCPEgrZxGGAf-t8jhz_eLMUyBN1IhNrdYDRcNHWvQcwNG9woI8CCVOUHG1YXudbaFIgUYvrCIevRWvb2ubhQAo-z0duD0rQjxIDBeKerVGkO3J2eXDwdraSioXbIWsdIPEN1s8pIwJIS2CPAgV2kB3n3JZ5HwBQjpRL1CWKnqvdCjZk3RcALk6N2wHigI8CB-wbljNlfqElD25uZkNg6taS81YDRU2vfMqGVQ420O9AjxWQEAAAABJM43UU6MLMRrPlCUqossvu1q_knons5yylyWTgxZzWUAAAAAAP7___8CLgABAAAAAAAWABQrYt3E7OllKRCEmL3FL589l78_5wAAAAAAAAAAImog8ATiyw4ACAjxILmbcIO7ixv3pCtwUMZ1VQGKus54F9lZ8-w5ECD5ZuiICAjwIG6ynCyFTLPE7Rgk-0ZGCtBDyqNQx8YvaSZNHy8D8p8jCAjwIMX8zoD2Be1YWvcx_bexVPRmBX0hK-do8b8t9SarimQVCAjxIG6XtpqIEclLlhzcK1LVjqoPGrjjmLnyno8tcETMzECECAjwIF6mlfXOFY51JhrK4eze8zQlKV75OYZYqbtyi8BWxmAsCAjwIKKUcJmVoz-u-geiRV_-ZHdF0VEPXaEPFWf_JX_0e7G2CAjxIGMeD0Z5QWNKBcAEpHht007FFIILW6aSJ8f3CMkKNsneCAjwIBFr6Je8rkB7kwhPGbq0yRgFwZsvW9JhY5sXDRtrq0QwCAjwIAHAwXaus-yUgKICJB5mVvx8VZuJgjwnpb0qWPg1pi6DCAjxIAJhb8cefkVHTAMymdsxa-_i-tUua62LcpALQnPG7R9_CAjwIDvsFqBhPfAL6TCtXZd7gBWmMpx6iiZ-Ug0Jf_LlcstgCAjwIDJRBX6Q0Vge-ra-k1_g76yJWTEp6WWF13I3JpTnsZPJCAjwILykZCbkC9VQgl5gytPKKir6T9nTvKR6y05iWSHBTQgzCAgABYiWDXPXGQED45c78Ah-sGbmQAwfZwjwEAYqxtHnZiPZnJEGPx_JvKsI8SDXkqDg17YsZIrEz5acRx7mBXCKW5mKNgRYnw_-U2cpDgjxBGrArDrwCEfK6Mono428_wCD3-MNLvkMji4taHR0cHM6Ly9hbGljZS5idGMuY2FsZW5kYXIub3BlbnRpbWVzdGFtcHMub3JnCPAg10nyJ6Jn4kshQQQCKE0Lvj3hBC6nLRBVIzaPV4eh8VwI8CCQaAqWlxEbac_XOq1MOlf9iOKHEsxXspzbjK0vLpy8BwjwII3iRbRXUcDxrhAdkZmFlI15nySCSEZ7g922tF1Xln5DCPEgYYvZ1L4v4rPu_UqLfcHPtwSb2OH2GhPgVcVhhH6DpkQI8CDZCIoR20sC-uchP40oAmcLm9EJFV7xzwplj54AeVadXQjxILvLBjPFpCoz29m9Yf2qRnV7PI9GqxE8ozVQfk9QwCqrCPEgZXcMudvEoB_MJ8tqOW2PLTKAIeQBnE-1bfzptRc2gR8I8VkBAAAAAfXq-bmxWqOz7B5wKkwjzHGv2R4s7Y0Z76LqXWYNhmz0AAAAAAD-____Av0cAAAAAAAAFgAUl-skmdZDtn7Hnub6mF4HP2uVn7oAAAAAAAAAACJqIPAE4MsOAAgI8CBDmQsbEXc46Hu8DivhCBM1LGExa4TTM-wo7HpoCVjBTQgI8CCty5vkQtPHzzs8xqArOYhVSjgaDoG1ou3cojv5_P7wQQgI8SDQWB0kdXCTwbk-TqTt0QfRMyzDNLOtU1XXFgvGSRlW8wgI8CC2PKa_QCIBZtrXodq1GdEzppISMsMRDOnzr2gFjLKOAAgI8CCwQ_QF67bcFk_uJ2s0VCZmf5PGIjTmTCpt_qnVY5p_8AgI8SAbzyx7z-oxPMju6PvtQhzrJIQyH2ZAc9oyLuYemzbmZQgI8CC5bh7J74uUk91r8LwybHQFCNBC3PWeuwtMCCNFKWj19AgI8SAf4R2TUNPjaX_PWDUImpoITK0JoW89zaMKnD1wlEEi8AgI8SC2vNmdm7eyP5Ytl1yTzT0njliMdALl1ViKG-s3bG2zswgI8CCpbIVNz1GFVXdJk2zd82hBUoNFFemUPBt7IJdWEOciPwgI8CBtYdRQcrtX1FtCm1SxF7sx-5cO04U8KzbJh8fqBkyReAgI8CBHs2LGmX6gI-lV7yp1RrV7_tGfdiBAwnEFF6B6yXHzAQgI8CATotVmbXBMAixhZ-QKy5Q4lR0FusdA_wcIC1TbB7GmxAgIAAWIlg1z1xkBA-KXOw"]},"log":{"leaf_index":"568","tree_size":"2123","proof":["f45b141c29a72d1dd42342346bb7fd12b66d73b89315738c5b7def3641b5f320","d4d7b8c6fd8965ea7cd8057e6f2a9412854c12ebb135fd06293711f02faa5e6b","beb0988209a78c612d94ef311d978f740c171410d1b6d8dc5d4434a0b246f0f9","d891a2f681bc6e2936edecb1511324b58e36833254bb256274badfb691a6610d","7bbff248bbe3191fd008692fa1133cb8467da28be2d23840cf64daaa59ff73c8","d51179e20cce7f7c89be598cfe03ff1e6b6aed9abab6697dc817cad0f13d732c","3e2f42ad699bdec235da1d2bfa42533abf32590a41496bba393972651e8eacb7","b0e100ab5ebcce5446b0b2d4ff6ac7d35040cb0c821edb28792fd1c81ccd1f6e","9f0db5cb2ee9169ea5d56ed30f68fa386251991cc487135832bf8c105dc92c96","14108339881e6713df1e6d34582069c609e80460dc60638e661361aa4403ff51","ec3fa24572dee1df200ec665f3e3244d925b199f0f84e225b820c3b66bd7b094","addcf2e0ff7974e4aa99af5e30d409f90d9f4311a4d85f5baf3e125eeb45b4c1"],"checkpoint":"pubphys.com/log/v1\n2123\npXVcluz7BF4vgChQs6lShuU0386gCH0RxrC1sxyE3rI=\n\n— pubphys.com/log/v1 JFPwIOLzsUD22XoTVyTfk/FMVj/u3f3DxZk4V/Ws10KVSS+8WQSwhunQ//EAhyS9Td5CyM0E++85GMezmKd8240j9Q8=\n","promise":null},"orcid_key_evidence":[],"attesting":null}