{"record":{"author":{"account_ref":null,"orcid":null},"builds_on":[],"content_schema":"pubphys.content.topic/1","content_sha256":"1420f29ec0abd140e041dd97ecc20759c9c098eef1f8c9015d8fa7a2f5a0feb3","created":"2026-10-03T07:17:50Z","files":[],"origin":{"assisted_by":[],"kind":"seed"},"parents":[],"salt":"fb2c636dd51830578e8b4020dbc7e7bb44689c9902ecb93bf0e3f8f200eb0db0","schema":"pubphys.record/2","site":"pubphys.com","target":null,"type":"topic"},"content":{"external_id":"chem.nonadiabatic-dynamics","field":"chem","n":"1","review_cite":"B. F. E. Curchod, T. J. Martinez, Ab Initio Nonadiabatic Quantum Molecular Dynamics, Chemical Reviews, 2018","review_link":"https://doi.org/10.1021/acs.chemrev.7b00423","review_verified":"true","summary":"When light hits a molecule, electrons and atomic nuclei move together in a way that breaks the usual assumption that electrons instantly follow the nuclei. Describing this coupled motion decides what happens in vision, photosynthesis, sunscreen molecules and organic electronics.","title":"Nonadiabatic molecular quantum dynamics","topic_ref":null,"why":"Photochemistry, energy and charge transport in molecular materials, radiation damage and ultrafast spectroscopy all require dynamics beyond the Born-Oppenheimer approximation (the assumption that electrons adjust instantly to nuclear positions)."},"attested":{"attestation":{"batch":null,"client_id":null,"id_token_sha256":null,"kind":"platform"},"record_hash":"aa1669ae0dd7fb5df9048991b7b6472f6d13dde0228a4ba5521d38de86ed2a38","schema":"pubphys.attested/1"},"envelope":{"attested_hash":"1ee463d84912d160eb46f195043b95f2cd6b0ae015c05e1f897f5bedeac2882b","platform_signature":{"key_id":"c6afc19b31429869751f06879c75cd64ea92654423d15b44be775bf1310a60da","sig":"2K2IBq7tmB5_obpSuRZTl4s-LNbLRYssbMg88o5XJJhXcGhinMVKJe9ZpSZWyTBj-fBQ_D2PnROKWkPa_ZlpCg"},"schema":"pubphys.envelope/1"},"record_hash":"aa1669ae0dd7fb5df9048991b7b6472f6d13dde0228a4ba5521d38de86ed2a38","leaf_index":110}