BIO In the literature: contested

What stabilizes the twist-bend nematic phase

In plain words

Bent-shaped molecules can form a nematic whose alignment spirals with a pitch of only about 100 Angstrom, the twist-bend nematic. Whether it forms because bending becomes energetically favourable or because of hidden polar order is disputed.

Precise statement

The twist-bend nematic $N_{\mathrm{TB}}$ (heliconical director, pitch about $8e-7\ \text{to}\ 1e-6\,\mathrm{cm}$ in CB7CB) was predicted from a negative bend elastic constant $K_{33} < 0$ and alternatively explained through coupling to local polar order or flexoelectricity. Determine which mechanism stabilizes $N_{\mathrm{TB}}$ and derive its coarse-grained elasticity (whether it behaves as a pseudo-layered smectic) from measured elastic constants and structure.

What would settle it

Measurement of the elastic constants and polar order through the $N$ to $N_{\mathrm{TB}}$ transition, compared with predictions of the competing theories.