What atoms tunnel in the two-level systems of amorphous silica? · revision history
Revision 2
Accepted · core change · record
Changes against revision 1:
- Title
- What atoms tunnel in the two-level systems of amorphous silica?
- Plain
- The tunneling model assumes small groups of atoms that flip between two nearly equal positions. Which atoms move, and how many, has never been identified in any glass.
- Precise · changed · core
- Revision 1: For amorphous SiO2 (and a-Si, a-Al2O3), identify the atomic configurations that form tunneling two-level systems with energies below $\sim 1e-4\,\mathrm{eV}$ ($\sim 1\,\mathrm{K}$), and reproduce their measured density of states $P$, deformation potential $\gamma \sim 0.5-1\,\mathrm{eV}$, electric dipole moments and isotope dependence.
- Revision 2: For amorphous $\mathrm{SiO_2}$ (and a-Si, a-Al2O3), identify the atomic configurations that form tunneling two-level systems with energies below $\sim 10^{-4}\,\mathrm{eV}$ ($\sim 1\,\mathrm{K}$), and reproduce their measured density of states $P$, deformation potential $\gamma \sim 0.5-1\,\mathrm{eV}$, electric dipole moments and isotope dependence.
- Settled by
- Atomistic simulation of a realistically quenched glass that finds tunneling double wells with the measured $P$, $\gamma$ and dipole moments, confirmed by an isotope-substitution or strain-spectroscopy experiment.
- Kind
- well-posed
- Answer type
- identification
- References
- (empty)
- Literature status
- open
- Status note
- (empty)
- Posed since
- (empty)
Decisions
- Accept · 2026-10-15 · record