Excitonic insulators and exciton condensates
In some materials, electrons and the holes they leave behind attract so strongly that they bind into excitons (electron-hole pairs) and open an energy gap on their own. If these pairs condense into one quantum state, they could flow without friction, much like a superfluid.
Why it matters
An exciton condensate would be a macroscopic quantum state of charge-neutral pairs, with possible dissipationless counterflow and energy transport.
Review
D. Jerome, T. M. Rice, W. Kohn, Excitonic Insulator, Physical Review, 1967. https://doi.org/10.1103/PhysRev.158.462 reference checked
Proof
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